Equilibria Flashcards

(38 cards)

1
Q

What is the formula for equilibrium constant?

A

Kc=products/[reactants](to the power of their stoichemtry.

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2
Q

What is a dynamic equilibrium?

A

it is a point in a reaction where the rate of the forward reaction is equal to the rate of the backward reaction in a closed system and the concentrations of the reactants and products are constant.

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3
Q

What is concentration?

A

the number of moles of a substance dissolved in 1dm^3 of solution

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4
Q

Why is the concentration of a solid constant?

A

because the density of a solid is constant

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5
Q

What is a mole fraction?

A

the number of moles of A divided by the number of moles in the mixture

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6
Q

How do you calculate the partial pressure of gas A?

A

Mole fraction of gas A * Total partial pressure

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7
Q

What only factor does the equilibrium constant depend on?

A

temperature

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8
Q

What happens to the equilibrium constant (K) in an endothermic and exothermic reaction when the temperature increases?

A

in an endothermic reaction the K increases and in an exothermic the K decreases

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9
Q

What is a homogeneous reaction?

A

When reactants and products are in the same phase

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10
Q

What is a heterogeneous reaction?

A

when the reactants and products are not in the same phase

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11
Q

how do you calculate Kc?

A

products to the power of their stoichiometry divided by the reactants to the power of their stoichiometry

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12
Q

What does Q(fraction to find Kc)=Kc mean?

A

the system is at dynamic equilibrium

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13
Q

What does Q(fraction to find Kc)<Kc mean?

A

the reaction is not at equilibrium and it favours the forward reaction to increase Q

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14
Q

What does Q(fraction to find Kc)>Kc mean?

A

the reaction is not at equilibrium and favours the backward reaction to decrease the Q

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15
Q

What is the order for calculating the Kc when moles are given?

A
  1. initial amount
  2. change
  3. equ. amount
  4. equ. concentration
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16
Q

What is Kpc (partition coefficient)?

A

the ratio of solute concentrations in two immiscible solvents.

17
Q

How do you calculate Kpc?

A

X in the organic layer divided by X in the aqueous layer

18
Q

What is Ksp (solubility product)?

A

the product of the concentrations of each ion in a saturated solution of a relatively souble salt

19
Q

What happens to Ksp when a compound dissolved endothermically and exothermically?

A

When it dissolves endothermically, Ksp increases, and when it dissolves exothermically, Ksp decreases

20
Q

True or False: acids are proton acceptors

A

FALSE, acids are proton donors whilst bases are acceptors

21
Q

What is a strong acid?

A

A acid that completely ionises in aqueous solutions

22
Q

How is pH calculated?

A

-log10[H3O+(aq)]

23
Q

How is Kw calculated?

24
Q

Why do Stronger acids conduct electricity better?

A

Because it has a higher concentration of H+ ions

25
What indicators to use for what pH ranges?
Methyl Orange for 3.1-4.4 and phenolphthalein for 8.3-10
26
What is Ka?
the equ. constant for the dissociation of a weak acid
27
How is Ka calculated?
HA + H2O ---> A- + H3O+ [A-][H3O+]/[HA]
28
what assumptions are made when calculating the pH of weak acids
1. [A-]=[H3O+] 2. [HA] initial = [HA]equilibrium
29
what is buffer solution?
a solution which resists change in the pH on addition of small quantities of acids or alkali
30
what is the buffer in human blood?
Hydrogen carbonate ions
31
What is the common ion effect?
an occurrance when adding a common ion in a solution reduces the solubility of a salt
32
How is the degree of solubility of Kpc determined?
by how strong the intermolecular bonds between solute and solvents are
33
What does it mean when the Kpc is less than 1 and greater than 1
the solute is more soluble in water than organic solvent and vis versa
34
What is a bronsted-lowry acid?
a species that can donate a proton
35
what is the formula for calculating pH of a buffer solution?
pH=pKa+log10[salt]/[acid]
36
expression for Ksp?
the products' concentration with their stoichiometry
37
What is a saturated solution?
a solution that contains the maximum amount of dissolved salt
38
What is the relationship between Ksp, Kc and Kstab?
Kc = Kstab * Ksp