Lec 1 Flashcards

(71 cards)

1
Q

The lining of the stomach contains cells that secrete a solution of HCl. Which drink would best alleviate heartburn, i.e., excess acid in the stomach?

A

milk of magnesia (pH 10.5)

stomach nature -> acidic

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2
Q

Which of the following is NOT an acid-base conjugate pair?
A. NH3 and NH4+
B. H2S and OH–
C. H2O and OH–
D. HCN and CN–

A

H2S and OH–

(no relation with each other)

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3
Q

When ammonium chloride hydrolyzes, the resulting solution will have a pH

A

<7

pH value of acidic is low, H+ is high if acidic

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4
Q

Which of the following conjugate acid/base pairs should be used to prepare a buffer with pH near 7.15

A

sodium dihydrogen phosphate and sodium hydrogen phosphate (pKa2 7.20)

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5
Q

What are the product(s) for the reaction between HNO3 and NH4OH?

A

NH4NO3 + H2O

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6
Q

When Cr3+ changes from an oxidation state of +3 to +6, Cr3+ will

A

lose 3 electrons

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7
Q

6 Strong Acids

A

HCl
HBr
HI
HClO4 an HClO3
H2SO4
HNO3

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8
Q

6 Strong Base

A

Li(OH)
Na(OH)
K(OH)
Mg(OH)2
Ca(OH)2
Ba(OH)2

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9
Q

1.How do you recognize an acid by formula

A

1.Starts with H

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10
Q

2.What ion do acids produce in water

A

2.H⁺ or H₃O⁺ ions

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11
Q

4.How do you recognize a base by formula

A

4.Ends with OH

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12
Q

5.What ion do bases produce in water

A

5.OH⁻ ions

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13
Q

7.How do you recognize a salt

A

7.Cation + anion not H⁺ or OH⁻ (e.g. NaCl)

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14
Q

8.Does the cation in a salt always come from a metal or base

A

8.Yes, usually from a metal or base

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15
Q

9.How do you recognize a carbonate

A

9.Contains CO₃²⁻

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16
Q

10.How do you recognize a bicarbonate

A

10.Contains HCO₃⁻

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17
Q

11.How do you recognize a metal

A

11.Element on the left of periodic table

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18
Q

12.How do you recognize a nonmetal

A

12.Element on the right of periodic table

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19
Q

13.What happens when acid and base react

A

13.Salt + water

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20
Q

14.What happens when acid and metal carbonate react

A

14.Salt + water + CO₂

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21
Q

15.What happens when acid and metal react

A

15.Salt + hydrogen gas

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22
Q

16.What happens when two salts react

A

16.Ion exchange, may form precipitate

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23
Q

17.What happens when hydrocarbon reacts with oxygen

A

17.Combustion forms CO₂ + H₂O

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24
Q

18.Identify the reaction 2Mg + O₂ → 2MgO

A

18.Combination / Synthesis

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25
22.What usually causes decomposition reactions to occur
22.Heat, light, or electricity
26
23.Write the decomposition of calcium carbonate
23.CaCO₃ → CaO + CO₂
27
24.Identify the reaction Zn + 2HCl → ZnCl₂ + H₂
24.Single displacement
28
25.In the reaction Zn + 2HCl → ZnCl₂ + H₂ which element is displaced
25.Hydrogen is displaced
29
29.Write the products of BaCl₂ + Na₂SO₄ → ?
29.BaSO₄ + 2NaCl
30
30.Identify the reaction H₂SO₄ + 2NaOH → Na₂SO₄ + 2H₂O
30.Neutralization
31
31.What are always formed in a neutralization reaction
31.Salt + water
32
32.What are the products of HCl + KOH
32.KCl + H₂O
33
33.Identify the gas evolved 2HCl + Na₂CO₃ → 2NaCl + H₂O + ?
33.CO₂ gas
34
34.What type of reaction occurs between acid and carbonate
34.Gas evolution
35
35.Write the products of H₂SO₄ + CaCO₃
35.CaSO₄ + H₂O + CO₂
36
36.Identify the products CH₄ + 2O₂ → ?
36.CO₂ + 2H₂O (combustion)
37
37.What are always produced in a complete combustion reaction
37.CO₂ and H₂O
38
38.What type of reaction is burning of propane
38.Combustion
39
41.What is the clue for a redox reaction
41.Change in oxidation number or electron transfer
40
42.What forms when AgNO₃(aq) reacts with NaCl(aq)
42.AgCl(s) + NaNO₃(aq)
41
43.How do you recognize a precipitation reaction
43.A solid (↓) forms from clear solutions
42
44.Name the precipitate in BaCl₂ + Na₂SO₄ → BaSO₄ + 2NaCl
44.BaSO₄
43
45.Identify the reaction 2H₂O₂ → 2H₂O + O₂
45.Decomposition / redox
44
47.Identify the product Cu²⁺ + 4NH₃ → ?
47.[Cu(NH₃)₄]²⁺
45
48.What is the clue that a complex is formed
48.Product inside square brackets
46
49.What type of reaction occurs inside a battery
49.Electrochemical (redox)
47
50.In Zn + Cu²⁺ → Zn²⁺ + Cu which is the anode
50.Zn is the anode
48
51.What type of reaction is rusting of iron
51.Redox (oxidation of Fe)
49
52.What type of reaction is photosynthesis
52.Combination (light-driven)
50
53.Which reaction type usually produces bubbles or fizzing
53.Gas evolution
51
54.Which reaction type is always exothermic
54.Combustion
52
55.Which reaction involves ion exchange and may form a precipitate
55.Double displacement
53
56.What is produced when acid reacts with carbonate
56.Salt + water + carbon dioxide
54
57.What are the products when base reacts with acid
57.Salt + water
55
The part of an electrochemical cell where oxidation occurs
anode
56
during the electroplating of silver, silver ions in solution
are reduced at the cathode
57
In an electrolytic cell, oxidation occurs
at the anode
58
product for: acid + metal carbonate/bicarbonate
59
product for: acid + metal
salt + H2 (gas)
60
Cu²⁺, Fe²⁺/Fe³⁺, Co²⁺, Ni²⁺, Zn²⁺, Ag⁺, Al³⁺, Cr³⁺, etc. added to ligand (NO2, NH3, SCN, CN, H2O, Cl, OH)
metal–ligand complex
61
62
1. Which of the following statements BEST describes a primary method? I. Set of instructions about how to carry out a method issued by a national standards body. II. It has the highest metrological qualities. III. Method that employs the use of materials such as certified reference materials. IV. Titration of hydrochloric acid with anhydrous sodium carbonate to determine the concentration of the acid is an example of this method.
II &IV
63
It is the fraction of the named material present in the stated chemical form.
PURITY
64
If you reported that a sample with 9 mg/L of a substance has only 5 mg/L and the acceptable limit according to standard is 7 mg/L, this is
FALSE +
65
It is a performance parameter that could be used to analyze a blank sample matrix.
Limit of detection
66
Which of the following factors affects the choice of analytical methods? A. The type of analysis required B. The accuracy required C. Possible interferences from components of the material other than those of interest. D. All of the above
All of the above
67
Chemical grade commonly used for low-grade applications such as cleaning and qualitative testing?
Technical Grade
68
In the determination of sugar concentration in powdered juice dissolved in water, which of the following is the matrix? A. sugar B. powdered juice C. water D. B and C
B and C
69
Which of the following is are TRUE about instrumental background signal? I. Even when no sample is being analyzed, the instrument will be generating a background signal. II. LOD for an instrument improves if the S/N can be increased. III. LOD for an instrument is not affected by S/N.
I AND II
70
The portion of the calibration curve which includes the range of concentrations of analyte that can be determined with demonstrated precision, accuracy, and response function.
Working range
71
The property of an analytical method to determine simultaneously several components independently from each other.
Selectivity