What is a lipid?
• Group of soluble substances in alcohol rather than water
• Include triglycerides, phospholipids, glycolipids and cholesterol
What is a macromolecule?
Very large, organic molecule
What is a phospholipid?
Molecule consisting of glycerol, two fatty acids and one phosphate group
What do lipids contain?
Lots of carbon and hydrogen, and smaller amounts of oxygen
Why are lipids insoluble in water?
Not polar
What are the three most important lipids in living things?
• Triglycerides
• Phospholipids
• Steroids
What are the three most important lipids examples of?
Macromolecules, as they aren’t polymers but have different components bonded together
How are triglycerides structured?
Made of glycerol and fatty acids (many different types)
What are essential fatty acids?
Fatty acids that we must ingest to get into our bodies, not made in our bodies
How is glycerol structured and what is it?
• Has 3 carbon atoms
• An alcohol (free –OH groups)
How are fatty acids structured?
Have carboxylic group on one end, attached to hydrocarbon tail
How long can a fatty acid hydrocarbon tail be?
2-20 carbons long
How are fatty acids acidic?
Carboxylic group ionises into H⁺ and –COO⁻ group
What does it mean if a fatty acid is saturated?
Has no C=C bonds in molecule
What does it mean if a fatty acid is unsaturated?
Has C=C bond, meaning fewer hydrogen atoms can bond to molecule
What does mono- and polyunsaturated mean?
• Monounsaturated is a single C=C bond
• Polyunsaturated is more than one C=C bond
What are the effects of more C=C bonds in a fatty acid hydrocarbon chain?
• Has kinks, pushing it apart slightly
• Makes it more fluid
• Lowers melting point (normally 20°C with less unsaturated)
What is an ester bond?
Condensation reaction between carboxilic fatty acid group and hydroxyl-glycerol group
What are waxes?
Type of lipid formed by combining fatty acids with alcohol molecules much larger than glycerol
How are triglycerides an energy source?
• Can be broken down in respiration to release energy, generating ATP
• Starts by hydrolysing ester bonds, then both glycerol and fatty acids can be broken down completely to carbon dioxide and water
How are triglycerides an energy store?
• As they’re insoluble in water, can be stored without affecting water potential of cell
• Mammals store fat in adipose cells under skin
How much energy does one gram of fat release?
Twice as much as one gram of glucose
Why does fat release twice as much energy as glucose?
Lipids have higher hydrogen atom proportions than carbohydrates, and almost no oxygen atoms
How are triglycerides good for insulation?
• Adipose tissue is storage location for lipids, acting as heat insulator
• Lipid in nerve cells acts as electrical insulator
• Animals preparing for hibernation store extra fat