Unit 7 Flashcards

(30 cards)

1
Q

2 electron domains, no lone pairs
EDG and MG

A

linear

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2
Q

3 electron domains, no lone pairs
EDG and MG

A

trigonal planar

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3
Q

4 electron domains, no lone pairs
EDG and MG

A

tetrahedral

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4
Q

5 electron domains, no lone pairs
EDG and MG

A

trigonal bipyramidal

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5
Q

6 electron domains, no lone pairs
EDG and MG

A

octahedral

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6
Q

3 electron domains, 1 lone pair EDG and MG

A

EDG: trigonal planar
MG: bent

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7
Q

4 electron domains, 1 lone pair
EDG and MG

A

EDG: tetrahedral
MG: trigonal pyramidal

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8
Q

4 electron domains, 2 lone pairs
EDG and MG

A

EDG: tetrahedral
MG: bent

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9
Q

5 electron domains, 1 lone pair
EDG and MG

A

EDG: trigonal bipyramidal
MG: seesaw

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10
Q

5 electron domains, 2 lone pairs
EDG and MG

A

EDG: trigonal bipyramidal
MG: T-shaped

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11
Q

5 electron domains, 3 lone pairs
EDG and MG

A

EDG: trigonal bipyramidal
MG: linear

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12
Q

6 electron domains, 1 lone pair
EDG and MG

A

EDG: octahedral
MG: square pyramid

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13
Q

6 electron domains, 2 lone pairs
EDG and MG

A

EDG: octahedral
MG: square planar

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14
Q

6 electron domains, 3 lone pairs
EDG and MG

A

EDG: octahedral
MG: T-shaped

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15
Q

6 electron domains, 4 lone pairs
EDG and MG

A

EDG: octahedral
MG: linear

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16
Q

molecular polarity depends on…

A

bond polarity and molecular geometry.

17
Q

bond polarity

A

A measure ofhow evenly electrons are shared in a chemical bond, determined by the difference in electronegativity between the bonded atoms.

18
Q

To be a polar MOLECULE a molecule must…

A
  1. have polar bonds.
  2. have the polar bonds arranged in a way that their polarity is not cancelled out (unsymmetrical electron cloud) –> non-symmetrical charge distribution –> dipole moment = polar molecule.
19
Q

To determine molecular polarity…

A
  1. Determine the VSEPR shape.
  2. Determine the bond polarity, draw the dipole moments.
  3. Sum all the dipole moments to determine the net dipole.
20
Q

Resonance structures

A

(Multiple) hybrid Lewis structures that show different possible arrangements of electrons in a molecule.

21
Q

When do resonance structures occur?

A

When there is more than one possible position of a double bond in a molecule.

22
Q

Resonance hybrid

A

An intermediate form of a molecule which exists when more than one valid Lewis formula can be drawn.
This form is more stable, as it has equal bond length and strength for each bond.

23
Q

What is one molecule that has resonance

A

Benzene (C6H6)

24
Q

Formal charge definition

A

The charge an atom would have if all the bonding electrons in the molecule were shared equally.

25
Formal charge equation
FC = V - (B+L) V = number of valence electrons in the unbonded atom (determined by the group number) B = number of bondinng pairs L = number of lone/non-bonded electrons
26
Which atom should have the more negative formal charge?
More electronegative atom.
27
Which atom should have the more positive formal charge?
Less electronegative atom.
28
Which atom should be the central atom?
The less electronegative atom (the atom with the ability to form the most bonds).
29
3 types of intermolecular forces
London dispersion forces Dipole-dipole (permanent or permanent-induced) Hydrogen bonding
30