alcohols Flashcards

(30 cards)

1
Q

What is the word equation for alcohol complete combustion?

A

Alcohol + O2 -> CO2 + H2O

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2
Q

What is the word equation for alcohol incomplete combustion?

A

Alcohol + O2 -> CO + H2O

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3
Q

Why is incomplete combustion of alcohols hazardous?

A

Produces carbon monoxide which is toxic

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4
Q

What are the conditions and reagents for alcohols to alkenes?

A

Phosphoric acid; Heat

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5
Q

What is the displayed formula equation for primary alcohol elimination to alkene?

A
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6
Q

Why will secondary and tertiary alcohols be able to produce multiple products?

A

The C=C bond can form from two carbons; they could have E/Z isomerism

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7
Q

What is the functional group of the alcohol homologous series

A

-OH (hydroxyl)

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8
Q

alcohol general formula

A

cnh2noh

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9
Q

primary alcohol

A
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10
Q

secondary alcohol

A
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11
Q

tertiary alcohol

A
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12
Q

Describing primary alcohol

A

If the carbon the -OH group is bonded to has two hydrogens bonded to it

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13
Q

Describing a secondary alcohol

A

If the carbon the -OH is bonded to has one hydrogen bonded to it

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14
Q

What is the way in which tertiary alcohols must be oxidised?

A

Combustion

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15
Q

Describing tertiary alcohol

A

If the carbon the -OH group is bonded to has no hydrogens bonded to it

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16
Q

Why are alcohols soluble

A

They contain an -OH (hydroxyl) group
The -OH group can form hydrogen bonds with the water

17
Q

Why do alcohols have higher boiling points than other homologous series

A

They contain an -OH (hydroxyl) group
The -OH group can form hydrogen bonds with other molecules
More energy is needed to break the hydrogen bonds than the London Forces in other homologous series

18
Q

Conditions, reagents and observations for primary alcohol oxidation to aldehydes

A

Potassium dichromate k2cr2O7
Sulfuric acid
Heat and distill
Potassium dichromate will turn orange to green

r-O-r

19
Q

Conditions, reagents and observations for primary alcohol oxidation to carboxylic acid

A

Add pottassium dichromate
Sulfuric Acid
Heat under reflux
Potassium dichromate will turn orange to green

20
Q

Structural and displayed formula equation for primary alcohol oxidation to aldehyde

21
Q

Conditions, observations and reagents for secondary alcohol oxidation to ketone

A

Potassium dichormate
Sulfuric Acid
Heat under reflux
Potassium dichromate will turn orange to green

22
Q

C=O group name

23
Q

suffix for aldehyde

24
Q

Structural and displayed formula equation for primary alcohol oxidation to carboxylic acid

25
ketone suffix
one
26
structural and displaced formula for alcohol to ketone
27
Why is there only one possible product of primary alcohol elimination to alkene
The C=C bond can only from from one carbon
28
conditions and reagents for alcohol to haloalkane
Sodium halide Sulfuric acid
29
What type of reaction is alcohol to haloalkane
Nucleophillic Substitution
30
Displayed formula equation for alcohol to haloalkane