aliphatic amines
N attached to straight/ branched chain (including non- aromatic rings
aromatic amines
N attached to aromatic ring
primary amine with Nh2 at end of chain
…… amine
primary amine with Nh2 on carbon not at end
..(number amine attached to).. amine…. alkyl chain.. .
2- amino propane
secondary/ tertiary amine containing same alkyl group
di/ tri…(Same alkyl group)… amine.
di methyl amine
secondary/ ternary amine containing different alkyl group
N-….extra group … longest chain.. amine
N- methyl ethyl amine
Amines behave as bases why
lone pair on N atom will accept H+
amines + acid –> (HCL)
salt
Nh3+cl-
formation of primary amines
1- formation of salt
haloalkane +nh3–> salt (Nh3+cl-)
2- formation of amine
salt +Na0H –> amine + h20 + NACl
formation of amines conditions
Nh3 in ethanol
formation of secondary amines
1- formation of salt
haloalkane +nh3–> salt (2chains - NH2+cl-)
2- formation of amine
salt +Na0H –> amine + h20 + NACL
ethanol used
prevenet reaction with h20 – substutate to forms a alcohol
excess ammonia used
prevents further substitution (avoids making secondary or tertiary amines)
formation of aromatic amines
explain why Nh2 on molecule can react with dilute HCL to form a salt
the lone pair on nitrogen can accept a proton