Chapter 4 - Electron Location Flashcards

(47 cards)

1
Q

What does the location of electrons in the electron cloud help us do?

A

Predict reactivity

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2
Q

Electromagnetic Radiation

A

-form of energy
-travels in waves

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3
Q

Speed of Light

A

-3.00 x 10^10 cm/s OR 3.00 x 10^8 m/s
-C=λν

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4
Q

Wavelength

A

-λ (lambda)
-distance between corresponding points on adjacent waves

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5
Q

Frequency

A

-ν (nu)
- # of waves that pass a given point in a specific amt. of time, usually one second
-SI unit for frequency is a Hertz

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6
Q

Hertz

A

1 Hertz = 1 wave/sec = 1/sec

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7
Q

Continuous Spectrum

A

a spectrum in which all wavelengths within a given range are included

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8
Q

Wave/energy theory of Light

A

-moved w/ wavelength + frequency
- has no standing mass
- de-localized (everywhere - no definite spot)
- Young double-split experiment

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9
Q

Particle/matter

A

-exists in tiny bundles (photons)
-photons possess energy
-photoelectric effect

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10
Q

Photoelectric effect

A

-emission of electons by certain metals when light shines on them
- dependent on frequency of light
-particle/matter theory

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11
Q

electromagnetic spectrum

A

consists of all electromagnetic radiation, arranged according to increasing wavelengths

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12
Q

Max Planck

A

when hot objects lose heat it is not continuous - it is lost in small specific amts. called QUANTA

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13
Q

Quantum

A

a finite quantity of energy that can be gained/lost by an atom

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14
Q

Photon

A

-a particle of electromagnetic radiation carrying a quantum of energy
-smallest piece of energy

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15
Q

E = hν

A

E - energy of a photon

h - Planck’s constant

ν - frequency of radiation (1/s)

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16
Q

Energy level

A

ex : n=3

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17
Q

Energy level orbital

A

ex: 3s ; 3p ; 3d

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18
Q

What was the Neil Bohr Model based on?

A

Solar System

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19
Q

Niel Bohr Model

A

1) electrons orbit the nucleus in set paths (orbit is a 2D path)

2) total energy of an electron increases as it moves farther from the nucleus

*Only worked for H atom

20
Q

Bohr’s approach did not explain

A

1) spectators of atoms w/ more than 1 electron

2) chemical behaviors of an atom

21
Q

Visible Light

A

emitted when an electron passes from a state of higher energy to a state of lower energy

22
Q

Ground State

A

state of lowest energy of an atom

23
Q

Excited State

A

state in which an atom has a higher potential energy than it has in its ground state

24
Q

Visible Light Is Produced when:

A

1) atom is at ground state

2) energy is added to atom + electrons absorb energy

3) electrons gain energy + jump to higher energy levels (excited state)

4) electrons do not have enough energy to stay in excited state they fall back down to ground state

5) any extra energy electrons have is emitted … thus a quantum of energy (light) is given off

25
Line spectrum
produced when an electron drops from a higher energy orbit to a lower energy orbit
26
Spectroscope
an instrument that separates light into a spectrum that can be explained
27
Line-Emission Spectra
of a certain substance identifies atom in that substance
28
What is Plank's Constant
6.626 x 10^-34 Joules • sec
29
Louis de Brogile
proposed electrons may have wave/particle nature
30
Erwin Schrödinger
devised equation that treated electrons moving around nuclei as waves works for all atoms
31
Quantum Theory
describes mathematically wave properties of electrons and other very small particles Schrodingers equation laid foundation
32
Schrodingers model
nucleus surrounded by orbitals, not orbits
33
Shriner and Bohr agree that.
electrons in orbitals closer to nucleus have lower energy
34
Heisenberg Uncertainty Principle
it is not possible to know both the position and velocity of electron at same time
35
Quantum numbers
specify properties of atomic orbitals and their electrons and their probable location
36
Principal
how close electron is to nucleus and energy level
37
Angular momentum
shape of sublevel
38
magnetic
# of orientations/orbitals of each sub level
39
Spin
rotation of electron
40
Aufbau principal
an electron occupies the lowest energy level orbital
41
Hunds rule
orbitals of = energy are each occupied by 1 electron before any one orbital is occupied by a 2nd electron and must have same spin
42
Paulis Exclusion principal
no 2 elections in same aton can have the same set of quantum #s
43
E- configuration
1s^2
44
orbital notation
<>/1s
45
Lewis Dot/ electron dot
only shows valence e-
46
V.L.S.
Red - longest wavelengths and least amt of energy Violet - shortest wavelengths and most amount of energy
47
Electromagnetic Spectrum
long waves - longest wavelength and least amount of energy Gamma - shortest wavelength and most energy