halogenation Flashcards

(13 cards)

1
Q

what type of halogenation involves Br2

A

Bromination

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2
Q

what would happen if a different halogen/alkene was used

A

the steps would be exactly the same, only a different product would form

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3
Q

what test does bromination explain

A

the bromine water test

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4
Q

draw the reaction mechanism for bromination

A
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5
Q

1) what happens as the Br molecule approaches the C=C bond

A

The electron rich π bond(in the C=C bond in ethene) induces a temporary dipole in the Br molecule

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6
Q

2) what happens to the electrons in the Br-Br bond and what does this cause

A

They are pushed away(repelled), making the nearer Br atom δ⁺ (electron deficient) and the further Br atom becomes δ⁻ (electron rich)

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7
Q

3) what does Brδ⁺ do and what happens at the same time

A

It acts as an electrophile. The electron pair from the π bond attacks Brδ⁺. At the same time, the electron pair in the Br-Br bond moves entirely onto Brδ⁻, causing the bond to break heterolytically.

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8
Q

4) what happens to the carbon atoms in the C=C bond

A

One carbon on the C=C bond forms a bond to Br, the other one becomes a carbocation.

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9
Q

5) what is now formed

A

an intermediate containing a carbocation is formed, a bromonium ion

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10
Q

6) what happen to Brδ⁻

A

Brδ⁻ becomes a bromide ion and acts as a nucleophile, attacking the carbocation in the bromonium ion

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11
Q

7) what product formed

A

a stable product has formed 1,2-dibromoethane(a HALOALKANE)

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12
Q

are nucleophiles exclusive to nucleophilic substitution

A

no

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13
Q

bromination turns alkenes into

A

Haloalkanes

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