Alkene
Hydrocarbon containing al lease one double bond (C=C)
Aliphatic unsaturated compounds
sp2 hybridization(Trigonal planar shaped,120)
Alkene are ______ compound.
Aliphatic unsaturated compounds
Hybridization of alkenes & its structure and bond angle
sp2 hybridization
Trigonal planar shaped,120
General formula of alkene
CnH2n
Alkenes are _______molecules.
electron-rich (Nucleophile)
Bonds in alkene
sp2 & double bond
(one sigma bond & one pi bond)
Double bond is electron rich bcus of the movement of electrons in pi bond
Alkene can bind with
Electrophile molecule (electron-deficient)
Melting point & boiling point of alkene
Increase with increased no of C & H
Physical properties are increase with increased C & H
Structural isomer of Butene
But-1-ene
But-2-ene
Structural isomer of Propene
Pent-2-ene
Pent-1-ene
Isomers of alkenes
1)Structural isomer
a.Chain isomers
b.Position isomers
2)Stereoisomerism
a.Cis-Trans isomers
b.E/Z isomers
Stereoisomerism is
isomer due to restricted rotation around double bond
Chain isomers of alkenes
Carbon skeleton is arranged differently
eg.But-1-ene & 2-methylprop-1-ene
Position isomer of alkenes
Position of double bond in alkenes
eg.But-1-ene & But-2-ene
Cis-trans isomers of alkenes
Cis isomer-2 similar gp on same side of double bond
Tran isomer-2 similar gp on opposite side with double bond
E/Z isomers of alkenes
E isomer-high priority gp are on opposite sides
Z isomer-high priority gp are on the same side
Priority rule
1)Atom with higher atomic number
2)Atom with longer carbon chain
Cycloalkenes
Unsaturated hydrocarbon containing one or more double bond within the righ structure
General formula for cycloalkene
CnH2n-2 (For monocyclic cycloalkenes with only one double bond)
Chemical properties of alkenes
Addition reactions
-Addition of hydrogen (hydrogenation)
-Addition of halogen (halogenation)
-Addition of hydrogen halides (Hydrohaligenation)
-Addition of water (Hydration)
-Polymerization of alkenes
Addition reaction of alkenes
-Addition of hydrogen (hydrogenation)
-Addition of halogen (halogenation)
-Addition of hydrogen halides (Hydrohaligenation)
-Addition of water (Hydration)
-Polymerization of alkenes
Addtion of hydrogen to alkene and cycloalkenes result in
Alkene+H2——>alkane
Cyclealkene+H2——>Cycloalkane
Hydrogenation of alkene
Addition of hydrogen
Catalyst-Nickel in 150 degree
Alkene+H2——>alkane
Cyclealkene+H2——>Cycloalkane
Halogenation of alkene
Reaction takes place at room temperature
(alkane-require UV light for halogenation)