Alkenes Flashcards

(36 cards)

1
Q

Alkene

A

Hydrocarbon containing al lease one double bond (C=C)
Aliphatic unsaturated compounds
sp2 hybridization(Trigonal planar shaped,120)

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2
Q

Alkene are ______ compound.

A

Aliphatic unsaturated compounds

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3
Q

Hybridization of alkenes & its structure and bond angle

A

sp2 hybridization
Trigonal planar shaped,120

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4
Q

General formula of alkene

A

CnH2n

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5
Q

Alkenes are _______molecules.

A

electron-rich (Nucleophile)

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6
Q

Bonds in alkene

A

sp2 & double bond
(one sigma bond & one pi bond)

Double bond is electron rich bcus of the movement of electrons in pi bond

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7
Q

Alkene can bind with

A

Electrophile molecule (electron-deficient)

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8
Q

Melting point & boiling point of alkene

A

Increase with increased no of C & H

Physical properties are increase with increased C & H

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9
Q

Structural isomer of Butene

A

But-1-ene
But-2-ene

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10
Q

Structural isomer of Propene

A

Pent-2-ene
Pent-1-ene

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11
Q

Isomers of alkenes

A

1)Structural isomer
a.Chain isomers
b.Position isomers
2)Stereoisomerism
a.Cis-Trans isomers
b.E/Z isomers

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12
Q

Stereoisomerism is

A

isomer due to restricted rotation around double bond

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13
Q

Chain isomers of alkenes

A

Carbon skeleton is arranged differently
eg.But-1-ene & 2-methylprop-1-ene

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14
Q

Position isomer of alkenes

A

Position of double bond in alkenes
eg.But-1-ene & But-2-ene

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15
Q

Cis-trans isomers of alkenes

A

Cis isomer-2 similar gp on same side of double bond
Tran isomer-2 similar gp on opposite side with double bond

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16
Q

E/Z isomers of alkenes

A

E isomer-high priority gp are on opposite sides
Z isomer-high priority gp are on the same side

17
Q

Priority rule

A

1)Atom with higher atomic number
2)Atom with longer carbon chain

18
Q

Cycloalkenes

A

Unsaturated hydrocarbon containing one or more double bond within the righ structure

19
Q

General formula for cycloalkene

A

CnH2n-2 (For monocyclic cycloalkenes with only one double bond)

20
Q

Chemical properties of alkenes

A

Addition reactions
-Addition of hydrogen (hydrogenation)
-Addition of halogen (halogenation)
-Addition of hydrogen halides (Hydrohaligenation)
-Addition of water (Hydration)
-Polymerization of alkenes

21
Q

Addition reaction of alkenes

A

-Addition of hydrogen (hydrogenation)
-Addition of halogen (halogenation)
-Addition of hydrogen halides (Hydrohaligenation)
-Addition of water (Hydration)
-Polymerization of alkenes

22
Q

Addtion of hydrogen to alkene and cycloalkenes result in

A

Alkene+H2——>alkane
Cyclealkene+H2——>Cycloalkane

23
Q

Hydrogenation of alkene

A

Addition of hydrogen
Catalyst-Nickel in 150 degree

Alkene+H2——>alkane
Cyclealkene+H2——>Cycloalkane

24
Q

Halogenation of alkene

A

Reaction takes place at room temperature

(alkane-require UV light for halogenation)

25
Hydrohalogenation of symmetrical alkene
26
Hydrohalogenation of asymmetrical alkene
*produce 2 products(One with more stable structure will be major product)
27
Hydration reaction of alkene
2 steps 1)Addition of H2SO4 (H & HSO4) 2)Addition of water (H & OH)
28
Hydration of alkene will produce
alcohol
29
Polymerization of ethene and propene
Ethene-polyethene or polythene Propene-polypropene
30
Classification of alkenes
1)Primary alkenes 2)Secondary alkenes 3)Tertiary alkenes 4)Quaternary alkenes
31
Primary alkenes
One gp is attached to double bonded carbon
32
Secondary alkenes
2 gp attached to double bonded carbon
33
Tertiary alkenes
3 gp attached to double bonded carbon
34
Quaternary alkenes
4 gps attached to double bonded carbon
35
Physical properties of alkene
1)Nonpolar 2)Insoluble in water 3)Low bp (London dispersion force) 4)Low density than water
36
State of alkene
2-5>gas 5-15>liquid above 16>solid