Arenes
Cyclic unsaturated hydrocarbon that are derived from benzene,C6H6
Aromatic compounds
Contain phenyl functional gp,C6H5
Arenes are ______ compounds.
Aromatic compound
Cyclic unsaturated
Functional gp of arenes
C6H5 phenyl
Benzene
Hezagonal ring of six carbon contain alternating double bonds
Each carbon of benzene ring is _____ hybridization.
sp2 hybridization (120)
Bonds in benzene
3 single bonds (3 sigma bonds)
3 double bonds (3 sigma bonds & 3 pi bonds)
All bonds are equal in length
In benzene ring,each p orbital is _______ to six-membered ring.
perpendicular
Benzene rings contain ______ electrons.
delocalized pi electrons and they are equally shared in the ring structure.Therefore,bonds in benzene are equal in length.
Physical properties of benzene
1)Colorless liquid
2)Highly flammable
3)Insoluble in water (non polar molecule)
4)Soluble in organic solvent
Chemical properties of benzene
Electrophilic substitution
a.Halogenation
b.Nitration
c.Sulfonation
d.Alkylation
e.Aceylation
Not undergoes addition (hydrogenation) reaction at normal temperature
Why benzene don’t undergoes addition reaction easily?
Bcus it would disrupt the aromatic ring stability
Halogenation of benzene
Addition of Halogen
Catalyst-AlCl3 in dry ether
Nitration of benzene
Addition of nitric acid
Catalyst-conc H2SO4 at 50 degree
Product-Nitro benzene
Sulfonation of benzene
Addition of sulfuric acid
Catalyst-heat
Product-Benzene sulfonic acid