Arenes Flashcards

(14 cards)

1
Q

Arenes

A

Cyclic unsaturated hydrocarbon that are derived from benzene,C6H6
Aromatic compounds
Contain phenyl functional gp,C6H5

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2
Q

Arenes are ______ compounds.

A

Aromatic compound
Cyclic unsaturated

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3
Q

Functional gp of arenes

A

C6H5 phenyl

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4
Q

Benzene

A

Hezagonal ring of six carbon contain alternating double bonds

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5
Q

Each carbon of benzene ring is _____ hybridization.

A

sp2 hybridization (120)

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6
Q

Bonds in benzene

A

3 single bonds (3 sigma bonds)
3 double bonds (3 sigma bonds & 3 pi bonds)

All bonds are equal in length

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7
Q

In benzene ring,each p orbital is _______ to six-membered ring.

A

perpendicular

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8
Q

Benzene rings contain ______ electrons.

A

delocalized pi electrons and they are equally shared in the ring structure.Therefore,bonds in benzene are equal in length.

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9
Q

Physical properties of benzene

A

1)Colorless liquid
2)Highly flammable
3)Insoluble in water (non polar molecule)
4)Soluble in organic solvent

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10
Q

Chemical properties of benzene

A

Electrophilic substitution
a.Halogenation
b.Nitration
c.Sulfonation
d.Alkylation
e.Aceylation

Not undergoes addition (hydrogenation) reaction at normal temperature

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11
Q

Why benzene don’t undergoes addition reaction easily?

A

Bcus it would disrupt the aromatic ring stability

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12
Q

Halogenation of benzene

A

Addition of Halogen
Catalyst-AlCl3 in dry ether

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13
Q

Nitration of benzene

A

Addition of nitric acid
Catalyst-conc H2SO4 at 50 degree
Product-Nitro benzene

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14
Q

Sulfonation of benzene

A

Addition of sulfuric acid
Catalyst-heat
Product-Benzene sulfonic acid

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