Alkynes
Hydrocarbon containing at least one triple bond
Aliphatic unsaturated hydrocarbon
sp hybridization (linear shape,180)
Alkynes are _________ compound.
Aliphatic unsaturated hydrocarbon
Hybridization,bond angle & shape of alkynes
sp hybridization
linear shape,180
General formula of alkynes
CnH2N-2
Bonds in alkynes
Triple bond
1 sigma & 2 pi bonds
IUPAC nomenclature of alkyne
—yne
Common nomenclature of alkyne
——acetylene
Common name of ethyne
Acetylene
Common name of 1-butyne
Ethylacetylene (Terminal alkyne)
Common name of 2-pentyne
Ethylmethylacetylene (internal alkyne)
Common name of 4-methyl 2-hexyne
sec-butylmethylacetylene (Second position mhr chain fil twr loh)
Chemical properties of alkynes
Addition reactions
-Addition of hydrogen (hydrogenation)
-Addition of halogen (halogenation)
-Addition of hydrogen halides (Hydrohaligenation)
-Addition of water (Hydration)
Catalyst of hydration of alkynes
H2SO4 (H & HSO4)
Hydration of alkynes with terminal alkyne will produce
Aldehyde (CHO)
Hydration of alkynes with internal alkyne will produce
Ketone (CO)
Classification of alkynes
1)Primary alkynes
2)Secondary alkynes
Tertiary & quaternary structure are not possible in alkynes bcus of sp hybridization
Primary alkynes
One gp is attached to triple bonded carbon
Secondary alkynes
2 gp are attached to triple bonded carbon
Physical properties of alkynes
1)Nonpolar
2)Insoluble in water
3)Soluble in organic solvent
4)Low bp
State of alkynes
2-4>gases
4-8>liquid
above 8>solid
Halogenation of alkynes
Hydrohalogenation of alkyne