Alkynes Flashcards

(22 cards)

1
Q

Alkynes

A

Hydrocarbon containing at least one triple bond
Aliphatic unsaturated hydrocarbon
sp hybridization (linear shape,180)

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2
Q

Alkynes are _________ compound.

A

Aliphatic unsaturated hydrocarbon

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3
Q

Hybridization,bond angle & shape of alkynes

A

sp hybridization
linear shape,180

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4
Q

General formula of alkynes

A

CnH2N-2

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5
Q

Bonds in alkynes

A

Triple bond
1 sigma & 2 pi bonds

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6
Q

IUPAC nomenclature of alkyne

A

—yne

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7
Q

Common nomenclature of alkyne

A

——acetylene

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8
Q

Common name of ethyne

A

Acetylene

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9
Q

Common name of 1-butyne

A

Ethylacetylene (Terminal alkyne)

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10
Q

Common name of 2-pentyne

A

Ethylmethylacetylene (internal alkyne)

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11
Q

Common name of 4-methyl 2-hexyne

A

sec-butylmethylacetylene (Second position mhr chain fil twr loh)

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12
Q

Chemical properties of alkynes

A

Addition reactions
-Addition of hydrogen (hydrogenation)
-Addition of halogen (halogenation)
-Addition of hydrogen halides (Hydrohaligenation)
-Addition of water (Hydration)

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13
Q

Catalyst of hydration of alkynes

A

H2SO4 (H & HSO4)

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14
Q

Hydration of alkynes with terminal alkyne will produce

A

Aldehyde (CHO)

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15
Q

Hydration of alkynes with internal alkyne will produce

A

Ketone (CO)

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16
Q

Classification of alkynes

A

1)Primary alkynes
2)Secondary alkynes

Tertiary & quaternary structure are not possible in alkynes bcus of sp hybridization

17
Q

Primary alkynes

A

One gp is attached to triple bonded carbon

18
Q

Secondary alkynes

A

2 gp are attached to triple bonded carbon

19
Q

Physical properties of alkynes

A

1)Nonpolar
2)Insoluble in water
3)Soluble in organic solvent
4)Low bp

20
Q

State of alkynes

A

2-4>gases
4-8>liquid
above 8>solid

21
Q

Halogenation of alkynes

22
Q

Hydrohalogenation of alkyne